Gas chemistry - (CCEA)

Part ofChemistry (Single Science)Unit 2: Further chemical reactions, rates and equilibrium, calculations and organic chemistry

What are the key learning points about gas chemistry?

  • The Earth’s consists of a mixture of gases: nitrogen, oxygen, carbon dioxide, argon and other , and water vapour.

  • Nitrogen is a highly unreactive gas that used as a coolant and in food packaging.

  • Ammonia is a pungent gas that is reacted to make ammonium salts that can be used as .

  • Hydrogen is a gas that can be prepared from the reaction of magnesium or zinc with hydrochloric acid. It is used in weather balloons.

  • Oxygen is a gas that reacts with many elements to produce and basic . It is used in .

  • Carbon dioxide is an acidic gas that can be tested for by bubbling through limewater. It is used in fizzy drinks.

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What gases are in the atmosphere?

The Earth’s atmosphere consists of the following gases:

  • 78% nitrogen

  • 21% oxygen

  • 0.03% - 0.04% carbon dioxide

  • about 1% argon

  • small proportions of other ; and

  • varying proportions of water vapour.

Can you order the gases in the Earth's atmosphere?

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What type of gas is nitrogen?

Nitrogen is the most abundant gas in the Earth’s atmosphere.

It is an example of a element (N2).

What are nitrogen's physical properties?

Nitrogen is:

  • colourless

  • odourless

  • in water; and

  • very unreactive.

How reactive is nitrogen?

Nitrogen is a highly unreactive gas:

  • A nitrogen molecule has a strong triple between the nitrogen atoms.

  • This strong triple covalent bond requires a large of amount energy to break before the nitrogen atoms can react with other atoms.

What is nitrogen used for?

We use nitrogen in two main ways:

  • Liquid nitrogen is very cold and is a good coolant.

  • Nitrogen gas provides an inert (unreactive) atmosphere in food packaging, helping to keep the contents fresh.

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What type of gas is ammonia?

Ammonia gas (NH3) is a compound that can be produced from the reaction of nitrogen and hydrogen.

What are ammonia's physical properties?

Ammonia is:

  • pungent
  • soluble in water; and
  • less dense than air.

How to test for ammonia

Method: Dip a glass rod in concentrated hydrochloric acid and put this in a sample of the gas.

Result: If ammonia is present, a white fumes of ammonium chloride is observed.

Equation: NH3(g) + HCl(g) → NH4Cl(s)

What is ammonia used for?

When ammonia reacts with an acid, an ammonium salt is produced.

Ammonium salts are used as .

There are three common acids, hydrochloric acid (HCl), nitric acid (HNO3) and sulfuric acid (H2SO4), each of these acids will react with ammonia to produce a different salt.

Here are the reactions to make three different ammonium salts:

  • ammonium chloride: NH3 + HCl → NH4Cl

  • ammonium nitrate: NH3 + HNO3 → NH4NO3

  • ammonium sulfate: 2NH3 + H2SO4 → (NH4)2SO4

The ammonium salts are very soluble in water, so they can dissolve in soil water and be absorbed by plants – this makes them useful as fertilisers.

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What type of gas is hydrogen?

Hydrogen is a light, gas that is another example of a diatomic element (H2).

What are the physical properties of hydrogen?

Hydrogen is:

  • colourless

  • odourless

  • insoluble in water; and

  • less dense than air.

How is hydrogen gas prepared and collected?

We prepare hydrogen by reacting zinc or magnesium with dilute hydrochloric acid:

Zn + 2HCl → ZnCl2 + H2

Mg + 2HCl → MgCl2 + H2

Hydrogen is insoluble in water, so it can be collected using a gas jar in a trough of water.

A gas jar is filled with water and placed on top of a beehive shelf.

The hydrogen gas passes through the delivery tube and displaces the water from the gas jar.

A thistle funnel is used so the hydrochloric acid can be added easily to the conical flask.

It is important that the end of the funnel is submerged in the acid or the hydrogen gas would escape the flask.

Apparatus used for preparing and then collecting hydrogen gas.

How to test for hydrogen

A lit splint applied to hydrogen gas will result in a popping sound.

What is hydrogen used for?

  • Making the fats in margarines solidify.

  • Weather balloons.

  • Hydrogen also has potential as a ‘clean fuel’ fuel for vehicles. The only product of the combustion of hydrogen is water which is non-polluting.

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What type of gas is oxygen?

Oxygen is a element (O2) that is essential for life on Earth.

What are the physical properties of oxygen?

Oxygen is:

  • colourless

  • odourless

  • denser than air; and

  • slightly in water.

How is oxygen prepared?

Oxygen can be made from hydrogen peroxide, which decomposes slowly to form water and oxygen:

hydrogen peroxide → water + oxygen

2H2O2(aq) → 2H2O(l) + O2(g)

The rate of reaction can be increased using a catalyst, manganese(IV) oxide.

(A catalyst is a substance that speeds up a reaction without being used up – it can be removed after this reaction is finished by filtration.)

Hydrogen peroxide is a colourless solution, and manganese(IV) oxide is a black solid.

To make oxygen in the laboratory the same apparatus that was used for the preparation of hydrogen is used.

Apparatus used for preparing and then collecting oxygen.

How to test for oxygen

A glowing splint applied to a sample of oxygen gas will relight.

What are the uses of oxygen?

  • Oxygen is used in medicine to help patients with breathing difficulties.

  • In welding, acetylene gas is mixed with oxygen to increase the burn temperature. Oxyacetylene welding is used to cut and weld steel.

How do other elements react with oxygen?

ElementTypeObservationsEquationNature of oxide
CarbonNon-metalCarbon glows orange when heated strongly, producing a colourless gas.C + O2 → CO2Acidic
SulfurNon-metalYellow solid melts to a red liquid and burns with a blue flame to produce a colourless pungent gas.S + O2 → SO2Acidic
MagnesiumMetalBurns with a bright white light, white solid formed.2Mg + O2 → 2MgOBasic
IronMetalBurns with orange sparks producing a black solid.3Fe + 2O2 → Fe3O4Basic
CopperMetalGlows red, occasionally with blue-green flame, forming a black layer on the metal surface.2Cu + O2 → 2CuOBasic

A basic oxide reacts with , and an acidic oxide reacts with .

Metals react with oxygen to produce basic oxides, while non-metals react with oxygen to produce acidic oxides.

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What type of gas is carbon dioxide?

Carbon dioxide (CO2) is a gas that is produced in many chemical reactions.

What are the physical properties of carbon dioxide?

Carbon dioxide is:

  • colourless

  • odourless

  • slightly soluble in water; and

  • more dense than air.

How is carbon dioxide prepared?

Carbon dioxide is prepared from the reaction of solid calcium carbonate and hydrochloric acid.

CaCO3(s) + 2HCl(aq) → CaCl2(aq) + CO2(g) + H2O(l)

It is prepared using the same apparatus that was used for hydrogen and oxygen.

Apparatus used for preparing carbon dioxide.

What is carbon dioxide used for?

  • Fizzy drinks.

  • Fire extinguishers – carbon dioxide is more dense than air so can sink and smother a flame.

How to test for carbon dioxide

Bubble the gas through limewater.

The limewater will change from colourless to milky if carbon dioxide is present.

Three test tubes used in a carbon dioxide test.
Image caption,
The limewater test for carbon dioxide.

How does carbon dioxide react with water?

Carbon dioxide reacts with water to form the weak acid, carbonic acid, H2CO3:

CO2 + H2O → H2CO3

Carbonic acid causes the acidity in fizzy drinks.

How does carbon dioxide react with limewater?

Carbon dioxide reacts with limewater (a solution of calcium hydroxide, Ca(OH)2), to form a white precipitate (appears milky) of calcium carbonate, CaCO3.

Ca(OH)2(aq) + CO2(g) → CaCO3(s) + H2O(l)

Adding more carbon dioxide results in the precipitate dissolving to form a colourless solution of calcium hydrogencarbonate.

CaCO3(s) + CO2(g) + H2O(l) → Ca(HCO3)2(aq)

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Prescribed practical C9: Investigate the reaction of gases

Please use the link below to access the article on: Prescribed practical C9 - Investigate the preparation, properties, tests and reactions of the gases hydrogen, oxygen and carbon dioxide

(https://www.bbc.co.uk/bitesize/articles/zt3fjfr)

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How much do you know about gas chemistry?

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