Chemical reactions of metals and non-metalsPhysical properties of the halogens

Group 1 contains reactive metals, group 7 contains reactive non-metals and group 0 contains unreactive non-metals. Reactivity increases down group 1 but up group 7. Many metals are transition metals.

Part ofChemistry (Single Science)Predicting and identifying reactions and products

Physical properties of the halogens

(IUPAC group 17) is a vertical column on the right of the . The in group 7 are called the .

Periodic table with Group 7 halogens coloured in red.
Figure caption,
Group 7 (IUPAC group 17) is on the right-hand side of the periodic table, next to group 0 (IUPAC group 18)

The halogens show trends in their physical and chemical .

Physical properties

The halogens exist as simple . Each molecule contains two halogen joined by a single . The table shows the colour and physical of chlorine, bromine and iodine at room temperature.

Group 7 elementColourState
Chlorine, Cl2Pale greenGas
Bromine, Br2BrownLiquid
Iodine, I2Purple-blackSolid
Group 7 elementChlorine, Cl2
ColourPale green
StateGas
Group 7 elementBromine, Br2
ColourBrown
StateLiquid
Group 7 elementIodine, I2
ColourPurple-black
StateSolid

The melting points and of the halogens increase going down group 7. This is because, going down group 7:

  • the molecules become larger
  • the become stronger
  • more is needed to overcome these forces

Example

The graph shows the melting and boiling points of the first four group 7 elements. Astatine is placed below iodine in group 7. Predict the melting and boiling points of astatine and its state at room temperature.

Bar chart showing how the melting and boiling points of the halogens increase going down group 7
Figure caption,
Bar chart showing how the melting and boiling points of the halogens increase going down group 7

Astatine should have a melting point of about 300°C and a boiling point of about 340°C. This means that it will be solid at room temperature.