Revise: Chemical energyCalculating enthalpy changes

Energy changes occur in chemical reactions as bonds are broken and new bonds formed. Enthalpy changes can be calculated from experimental data, and are independent of the route taken (Hess's Law).

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Calculating enthalpy changes

The for a reaction can be calculated using the following equation:

\(\Delta H=cm\Delta T\)

\(\Delta H\) is the enthalpy change (in kJ or kJ mol-1)

c is the specific heat capacity of water.

It is a constant, 4.18 kJ kg-1˚C-1 and is found in the data book.

m is the mass of water (in kg) (Remember that 100 cm3 = 0.1 kg)

\(\Delta T\) is the change in temperature (˚C)

Example

Question

A solution was made by dissolving a spatula of potassium nitrate into 50 cm3 of water. The temperature changed from 20.4˚C to 18.7˚C. Calculate the enthalpy change for this reaction.