Redox, rusting and iron - (CCEA)Preventing rusting

Oxidation is loss of electrons, gain of oxygen or loss of hydrogen. Reduction is gain of electrons, loss of oxygen or gain or hydrogen. Rusting is an example of oxidation.

Part ofCombined ScienceFurther chemical reactions, rates and equilibrium, calculations and organic chemistry

Preventing rusting

There are several ways to prevent iron and steel rusting. Some work because they stop oxygen or water reaching the surface of the metal:

  • oiling – for example, bicycle chains
  • greasing – for example, nut and bolts
  • painting – for example, car body panels
  • coating with a thin layer of plastic
Empty cans of food

Iron and steel objects may also be covered with a layer of metal. Food cans are plated with a thin layer of tin.

Galvanising

Galvanising is a method of rust prevention. The iron or steel object is coated in a thin layer of zinc. This stops oxygen and water reaching the metal underneath – but the zinc also acts as a sacrificial metal. Zinc is more reactive than iron, so it oxidises rather than the iron object.

Sacrificial protection - Higher tier

A reactivity series lists metals in order of how reactive they are.

Reactivity series

Magnesium and zinc are often used as . They are more reactive than iron and lose their electrons in preference to iron. This prevents iron from losing its electrons and becoming oxidised.