Investigating exothermic and endothermic reactions
Dr Maggie Aderin-Pocock and Dr Alex Lathbridge investigate exothermic and endothermic reactions
Endothermic and exothermic reactions
When a chemical reaction happens, energyThe capacity of a system to do work or the quantity required for mechanical work to take place. Measured in joules (J). For example, a man transfers 100 J of energy when moving a wheelbarrow. is transferred to or from the surroundings. For example, changes in heat energy happen in the following situations:
- saltThe substance formed when the hydrogen ion in an acid is replaced by a metal ion.dissolveWhen a substance breaks up and mixes completely with a solvent to produce a solution. in water
- neutralisationThe reaction between an acid and a base to form a salt plus water. reactions
- displacement reactionA reaction that occurs when a more reactive element replaces a less reactive element in a compound.
- precipitation reactionA reaction in which an insoluble solid is formed when certain solutions are mixed.
When these reactions happen in solution, there are temperatureHow warm or cold something is. changes that can be observed. These can be measured using a thermometerAn instrument used to measure temperature..
Reactions can be endothermicReaction in which energy is taken in. or exothermicReaction in which energy is given out to the surroundings. The surroundings then have more energy than they started with so the temperature increases.. The table shows some differences.
| Endothermic | Exothermic | |
| Heat energy | Taken in | Given out |
| Temperature of reaction mixture | Decreases | Increases |
| Heat energy | |
|---|---|
| Endothermic | Taken in |
| Exothermic | Given out |
| Temperature of reaction mixture | |
|---|---|
| Endothermic | Decreases |
| Exothermic | Increases |
The slideshow describes an exothermic reaction between dilute sodium hydroxide and hydrochloric acid, and an endothermic reaction between sodium carbonate and ethanoic acid.
Image caption, 1. Sodium hydroxide solution is poured into a beaker of hydrochloric acid which contains a thermometer showing room temperature
Image caption, 2. The beaker now contains sodium chloride and water, and the thermometer is showing a rise in temperature, so the neutralisation reaction is exothermic
Image caption, 3. Sodium carbonate powder is tipped into a beaker of ethanoic acid which contains a thermometer showing room temperature
Image caption, 4. The beaker now contains sodium ethanoate, water and carbon dioxide, and the thermometer is showing a fall in temperature, so this was an endothermic reaction
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In endothermic reactions, energy enters from the surroundings. In exothermic reactions, energy exits to the surroundings.
A study of the energy changes involved in chemical reactions, whether exothermic or endothermic
What an exothermic and an endothermic reaction is, and how temperature changes can be used to identify which reaction is which