The reactivity series of metalsEvidence for the reactivity series

The method used to extract metals depends on the reactivity of the metal. The reactivity series allows us to predict how metals will react.

Part ofChemistry (Single Science)Metals and their extraction

Evidence for the reactivity series

In a reactivity series, the most reactive is placed at the top and the least reactive element at the bottom. More reactive metals have a greater tendency to lose and form positive .

The reactivity series of metals

A list of elements from most reactive to least reactive: potassium, sodium, lithium, calcium, magnesium, aluminium, zinc, iron, copper, silver and gold.

A good way to remember the order of a reactivity series of metals is to use the first letter of each one to make up a silly sentence. For example: People Say Little Children Make AZebra Ill Constantly Sniffing Giraffes.

Observations of the way that these elements react with water, and steam enable us to put them into this series.

The tables show how the elements react with water and dilute acids:

ElementReaction with water
PotassiumViolently
SodiumVery quickly
LithiumQuickly
CalciumMore slowly
ElementPotassium
Reaction with waterViolently
ElementSodium
Reaction with waterVery quickly
ElementLithium
Reaction with waterQuickly
ElementCalcium
Reaction with waterMore slowly
ElementReaction with dilute acids
CalciumVery quickly
MagnesiumQuickly
ZincMore slowly
IronMore slowly than zinc
CopperVery slowly
SilverBarely reacts
GoldDoes not react
ElementCalcium
Reaction with dilute acidsVery quickly
ElementMagnesium
Reaction with dilute acidsQuickly
ElementZinc
Reaction with dilute acidsMore slowly
ElementIron
Reaction with dilute acidsMore slowly than zinc
ElementCopper
Reaction with dilute acidsVery slowly
ElementSilver
Reaction with dilute acidsBarely reacts
ElementGold
Reaction with dilute acidsDoes not react

The speed at which hydrogen bubbles are produced tells us how reactive a metal is with acid. The quicker the fizzing, the more reactive the metal.

Note that aluminium can be difficult to place in the correct position in the reactivity series during these experiments. This is because its protective aluminium oxide layer makes it appear to be less reactive than it really is. When this layer is removed, the observations are more reliable.

Non-metals in the reactivity series

It is useful to place carbon and hydrogen into the reactivity series because these elements can be used to extract metals.

Here is the reactivity series including carbon and hydrogen:

A list of elements from most reactive to least reactive: potassium, sodium, lithium, calcium, magnesium, aluminium, carbon, zinc, iron, hydrogen, copper, silver and gold.

Note that zinc and iron can be from their using carbon but not using hydrogen. However, copper can be extracted using carbon or hydrogen.