Alcohols and carboxylic acids - EdexcelCarboxylic acids

Alcohols contain the –OH functional group. Ethanol is made from sugars by fermentation, and concentrated using fractional distillation. Carboxylic acids contain the –COOH functional group.

Part ofChemistry (Single Science)Separate chemistry 2

Carboxylic acids

The form a . Like all homologous series, the carboxylic acids:

  • have the same
  • differ by CH2 in from neighbouring
  • show a gradual variation in , such as their
  • have similar

Functional group

The in the carboxylic acids is the group, –COOH. It is responsible for the typical reactions of carboxylic acids, which are weak . Vinegar is a dilute solution of ethanoic acid.

Structures

The table shows four carboxylic acids, their formulae and their structures.

Table of four carboxylic acids; methanoic acid, ethanoic acid, propanoic acid and butanoic acid, with their formula and structures.

Acid properties

The carboxylic acids have the typical properties of acids. For example, they:

  • in water to form with values less than 7
  • react with to form a and hydrogen
  • react with to form a salt and water
  • react with carbonates to form a salt, water and carbon dioxide

These properties are due to the –COOH functional group.