David Cameron is demanding a personal apology from Prime Minister Gordon Brown over e-mails sent by an adviser discussing smearing the Tories.
The Tory leader is "absolutely furious" and is calling on Mr Brown to give a guarantee that such messages will not be sent again, a spokeswoman said.
On Saturday, one of Mr Brown's closest advisors, Damian McBride, resigned from his post for sending the messages. Laura Kuenssberg reports.
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